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Photochemical reactivity of [RuII(L)(CO)2Cl2] and [Me4N] [RuII(L)(CO)Cl3] (L = 2,2′-bipyridine or 4,4′- di(isopropoxycarbonyl)-2,2′-bipyridine) in CH3CN and the redox properties of the resulting new complexes

✍ Scribed by Marie-Noëlle Collomb-Dunand-Sauthier; Alain Deronzier; Raymond Ziessel

Publisher: Elsevier Science
Year: 1993
Tongue: English
Weight: 833 KB
Volume: 444
Category: Article
ISSN: 0022-328X
DOI: 10.1016/0022-328x(93)83073-5

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## Abstract A series of new rhenium(I) complexes of the type [Re^I^(CO)~3~(L)(L′)]^__n__+^ (L = 2,2′‐biquinoline (bqui) or 3,3′‐(ethane‐1,2‐diyl)‐2,2′‐biquinoline (CH~2~CN~2~)bqui); L′ = CF~3~SO$\rm{\_3^ - }$, pyridine (py), or 4‐substituted pyridine (HOpy, Bzpy, or NCpy); __n__ = 0 or 1) were prep