These results demonstrate that such surfactant crown ethers and their complexes are suitable as model compounds for biogenic lipid molecules; this is important in as much as the fine structure of natural membrane-forming compounds could so far be determined only in very few cases and with limited ac
Photochemical Studies of cis(CO),trans(Cl)-[Ru(bpy)(CO)2Cl2] (bpy = 2,2′-bipyridine): Ligand Exchange Reactions in Methanol
✍ Scribed by Esa Eskelinen; Toni-J. J. Kinnunen; Matti Haukka; Tapani A. Pakkanen
- Publisher
- John Wiley and Sons
- Year
- 2002
- Tongue
- English
- Weight
- 280 KB
- Volume
- 2002
- Category
- Article
- ISSN
- 1434-1948
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📜 SIMILAR VOLUMES
Photoirradiation of the complex trans(Cl)-[Os(bpy)(CO) 2 Cl 2 ] in acetonitrile with λ Ն 320 nm light gives rise to substitution of a CO ligand, with the formation of trans(Cl)-[Os(bpy)-(CO)(CH 3 CN)Cl 2 ]. The bonding properties and redox reactions of the novel photoproduct were thoroughly investig
Aqueous hydrogen halides HX (X = Cl, Br, I) are shown to containing derivatives, but the only stable isomer containing iodine was trans(I)-Ru(dmbpy)(CO) 2 I 2 . The failure to obtain be excellent halogen sources for the synthesis of a series of halogen-containing ruthenium mono(2,2Ј-bipyridine) car-