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The trans influence of CF3: gas phase structure of CF3SF5

โœ Scribed by Colin J. Marsden; Dines Christen; Heinz Oberhammer

Publisher
Elsevier Science
Year
1985
Tongue
English
Weight
569 KB
Volume
131
Category
Article
ISSN
0022-2860

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Rate constant ratios, k d /k c , for the disproportionation/combination reaction at a temperature of 295 ฯฎ 2 K, have been measured as 0.034 ฯฎ 0.009 for the collision between CF 3 CH 2 CF 2 ฯฉ CF 3 radicals and as 0.075 ฯฎ 0.019 for CF 3 CH 2 CF 2 ฯฉ CF 3 CH 2 CF 2 radicals. The effect of the two fluori