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The gas phase structure of trifluoroethylidynesulfur trifluoride, CF3CSF3

✍ Scribed by D. Christen; H.G. Mack; H. Oberhammer; C.J. Marsden; K. Seppelt; H. Willner


Publisher
Elsevier Science
Year
1987
Tongue
English
Weight
46 KB
Volume
35
Category
Article
ISSN
0022-1139

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Reactions of CF3SF3NCF3 with nucleophil
✍ Shin-Liang Yu; Jean'ne M. Shreeve 📂 Article 📅 1976 🏛 Elsevier Science 🌐 English ⚖ 464 KB

The new compounds, CF3SF(0)=NCF3 and CF3SF(=NCH3)=NCF3, result from nucleophilic displacement reactions of CF3SF3=NCF3 with water and methylamine, respectively. Higher yields of the di-imine are obtained when CH3N(Si(CH3)3)2 is substituted for CH3NH2. Stable fluoroamines, CF3SF4N(F)Rf (Rf = CF3, C2F