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The thermolysis of 3-methylenebicyclo[3.2.1]oct-6-ene and of 3-oxobicyclo[3.2.1]oct-6-ehe

โœ Scribed by J. Japenga; M. Kool; G.W. Klumpp

Publisher
Elsevier Science
Year
1975
Tongue
French
Weight
114 KB
Volume
16
Category
Article
ISSN
0040-4039

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โœฆ Synopsis

In connection with our work on the thermal 1.3-carbon shifts of bicyclo[3.2.n1 alka-2,6-dienes (n = 1,2; cf. I+II)' we have also examined the thermal behaviour of 3-methylenebicgclo[3.2.l]oct-6-ene (IIIa)2 and of 3-oxobicyclo[3.2.1}act-6-ene (IIIb)3, which contain a double bond at C-3 in the exocyclic position. The study of these compounds is also of interest with regard to recent work on the structurally related 1.5-hexadiene derivatives IV -VI?,5

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