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Dynamic Effects on [3,3] and [1,3] Shifts of 6-Methylenebicyclo[3.2.0]hept-2-ene

✍ Scribed by Christopher P. Suhrada; Cenk Selçuki; Maja Nendel; Carina Cannizzaro; K. N. Houk; Peter-Jürgen Rissing; Dirk Baumann; Dieter Hasselmann


Publisher
John Wiley and Sons
Year
2005
Tongue
English
Weight
425 KB
Volume
44
Category
Article
ISSN
0044-8249

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Polymerization behavior of meta-naphthoquinone methide, 3,4-benzo-6methylenebicyclo[3.1.0]hex-3-ene-2-one ( 1), was studied. Radical initiator 2,2-azobis(isobutyronitrile) (AIBN) induced polymerization of 1, but ionic initiators potassium tert-butoxide, butyllithium, and boron trifluoride etherate d