Crystal and molecular structure of 3,3-diphenyl-3-phosphoniabicyclo[3.2.1]oct-6-ene bromide monohydrate
โ Scribed by Mazhar-Ul-Haque; William Horne; Sheldon E. Cremer; James T. Most
- Publisher
- Springer
- Year
- 1989
- Tongue
- English
- Weight
- 454 KB
- Volume
- 19
- Category
- Article
- ISSN
- 1572-8854
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In connection with our work on the thermal 1.3-carbon shifts of bicyclo[3.2.n1 alka-2,6-dienes (n = 1,2; cf. I+II)' we have also examined the thermal behaviour of 3-methylenebicgclo[3.2.l]oct-6-ene (IIIa)2 and of 3-oxobicyclo[3.2.1}act-6-ene (IIIb)3, which contain a double bond at C-3 in the exocycl
Previous studies (14) of B-diketones have shown that these compounds exist, in the solid, in the enolic form with localisation of the enolic hydrogen. In view of the similarities between the B-diketones and the monothio-f+diketones it was felt appropriate to investigate a representative monothio-8-