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The tetra­lithium derivative of the tetra­kis(1-naphthyl­imido)silicate tetra­anion

✍ Scribed by Copsey, May C. ;Balakrishna, Maravanji S. ;Chivers, Tristram

Book ID
104486962
Publisher
International Union of Crystallography
Year
2006
Tongue
English
Weight
231 KB
Volume
62
Category
Article
ISSN
1600-5368

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✦ Synopsis

The title compound, bis(diethyl ether-κ__O__)tetra(tetrahydrofuran-κ__O__)[μ~4~-tetrakis(1-naphthylimido)silane(4−)]tetralithium(I) diethyl ether solvate, [Li~4~(C~40~H~28~N~4~Si)(C~4~H~8~O)~4~(C~4~H~10~O)~2~]·C~4~H~10~O, has been structurally characterized. The compound contains the tetrakis(naphthylimido)silicate tetraanion, which is formally isoelectronic with the orthosilicate anion, [SiO~4~]^4−^. The two halves of the molecule are equivalent, related by a crystallographic twofold rotation axis.

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