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The thermal rearrangement of tetra-arylated dihydrosemibullvalene derivatives, and 1H/13C NMR-structure correlations

✍ Scribed by S. Greenfield; K. Mackenzie

Publisher
Elsevier Science
Year
1984
Tongue
French
Weight
248 KB
Volume
25
Category
Article
ISSN
0040-4039

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✦ Synopsis

A systematic study of the thermal cyclisation of isomeric di-p-anisyldiphenylcyclooctatriene derivatives, and of the facile isomerisation of the resulting dihydrosemibullvalenes, with 'H/13C nmr-structure correlations, supports earlier proposals for rearrangement mechanism.

In earlier papers 1,2,3 we described the reaction sequence illustrated in Scheme 1 4

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