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The “tert-amino effect” in heterocyclic chemistry: Synthesis of tetra- and pentacyclic compounds

✍ Scribed by W. H. N. Nijhuis; G. R. B. Leus; R. J. M. Egberink; W. Verboom; D. N. Reinhoudt

Book ID: 104589054
Publisher: Elsevier Science
Year: 2010
Tongue: English
Weight: 861 KB
Volume: 108
Category: Article
ISSN: 0165-0513
DOI: 10.1002/recl.19891080503

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TheMnal rearrangement of Z-viny&1-(I-pyrroZidinyZ)benzenes varies with the leaving grotrp ability of substituents in the viny2 moiety; compound.s 2 having an OR group give 9-(atkoccy-methyZ)pyrroZoCl,2-alindoZes and corrpounds 6\_ IX = OAc, OTs or CZ) yield I-aZkyZindoZes.