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Novel applications of the “t-amino effect” in heterocyclic chemistry; synthesis of 1-alkylindoles

✍ Scribed by W.C. Dijksman; W. Verboom; D.N. Reinhoudt; C.G. Hale; S. Harkema; G.J. van Hummel

Book ID
104241354
Publisher
Elsevier Science
Year
1984
Tongue
French
Weight
285 KB
Volume
25
Category
Article
ISSN
0040-4039

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✦ Synopsis

TheMnal rearrangement of Z-viny&1-(I-pyrroZidinyZ)benzenes varies with the leaving grotrp ability of substituents in the viny2 moiety; compound.s 2 having an OR group give 9-(atkoccy-methyZ)pyrroZoCl,2-alindoZes and corrpounds 6_ IX = OAc, OTs or CZ) yield I-aZkyZindoZes.

📜 SIMILAR VOLUMES

Novel applications of the “t-amino effec
Novel applications of the “t-amino effect” in heterocyclic chemistry. Synthesis of a pyrrolo[1,2-a]quinazoline and 5H-pyrrolo[1,2-a][3,1]benzothiazines
✍ W. Verboom; M.R.J. Hamzink; D.N. Reinhoudt; R. Visser 📂 Article 📅 1984 🏛 Elsevier Science 🌐 French ⚖ 260 KB

I-(l-PyrroZidinyZlbenzenes substituted with an inino-or an in situ generated thiocarbony2 group in the 2-position rearrange upon heating to quinazotine and benzothiazine derivatives, respectively.