✦ LIBER ✦

The temperature dependence of the reactions H2(v = 1) + D, H

✍ Scribed by V.B. Rozenshtein; Yu.M. Gershenzon; A.V. Ivanov; S.D. Il'in; S.I. Kucheryavii; S.Ya. Umanskii

Publisher: Elsevier Science
Year: 1985
Tongue: English
Weight: 339 KB
Volume: 121
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(85)87161-x

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✦ Synopsis

The lempernwre dependence OT the raw constant for the rcacrions H2( L: -l)+D and H2(u =l)+H was smdied using a flow-lube method combined with EPR and lhermome[ric techniques. The rale cons~an~s (in cm3/molecule s) were round LO be

k~=(2.3~1.3)x10-'0exp[-(32W~6DO)/RT

]. ~~=(1~0_5)X10~'"exp[-(3100~300)/RT~. k~~2_7xlO-" over the range 254-367 K for H,(u =l)+D and k," + kf'= (1.8~0.7)~10~'~ al 254 K and (3.9~1.0)~10-" a~ 298 K for Hl(u =l)+H.

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