Reevaluation of the temperature dependence of the reactions of Cl+ and HCl+· with H2
✍ Scribed by Paul R. Kemper; Michael T. Bowers
- Publisher
- Elsevier Science
- Year
- 1983
- Weight
- 361 KB
- Volume
- 51
- Category
- Article
- ISSN
- 0020-7381
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
The hyperspherical method has been used to perform a close coupling calculation on the HtHCl+H2tCI reaction. Partial reaction probabilities and integral and differential cross sections have been computed for energies ranging from threshold up to I eV.
Rate constants for reactions of SiFz radicals have been measured at 2 Torr in a high-temperature fast-flow system. The bimolecular reaction rate constant for SiF\*+F, over a temperature range of 282-617 K can be expressed as (1.0+0.25)X IO-"exp[ -(1850~2OO)lRT] cm3 molecule-' s-', where R is incal m
The lempernwre dependence OT the raw constant for the rcacrions H2( L: -l)+D and H2(u =l)+H was smdied using a flow-lube method combined with EPR and lhermome[ric techniques. The rale cons~an~s (in cm3/molecule s) were round LO be ## k~=(2.3~1.3)x10-'0exp[-(32W~6DO)/RT ]. ~~=(1~0\_5)X10~'"exp[-(3