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The √t law in solid-phase reactions. Analysis of the hypothesis on rate constant distribution

✍ Scribed by V. M. Zaskul'nikov; V. L. Vyazovkin; B. V. Bol'shakov; V. A. Tolkatchev

Publisher
John Wiley and Sons
Year
1981
Tongue
English
Weight
953 KB
Volume
13
Category
Article
ISSN
0538-8066

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✦ Synopsis

The reaction C2Hs + 0 2 -C2Hs02 in glassy methanol-d4 and the H-atom abstraction by CH:%, C ~H S , and n-C4Hy radicals in C ~H S O H + C2DsOH and CDBCH~OH + C ~D S O H glassy mixtures have been studied by electron spin resonance. The analysis of the dependence of the reaction rates on the concentration of 0 2 (oxidation) and CzHsOH, CD&HzOH (H-atom abstraction) has shown that the fi law is not conditioned by the existence of regions characterized by different rate constants.

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