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The √t law in solid-phase reactions verification of the √t law stability in h-atom abstraction reactions

✍ Scribed by B. V. Bol'shakov; A. A. Stepanov; V. A. Tolkatchev

Publisher
John Wiley and Sons
Year
1980
Tongue
English
Weight
471 KB
Volume
12
Category
Article
ISSN
0538-8066

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✦ Synopsis

Abstract

The law c = c~0~ exp(__K √t__) in the alkyl radical abstraction reaction is affected by neither the matrix annealing nor the way of the radical generation. If the reaction runs at varying temperature, a dimensionless time τ which does determine unambiguously the degree of conversion can be introduced.

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