The synthesis of α-stannyl-silanes and their use in the formation of alkenes
✍ Scribed by Anthony G.M. Barrett; Jason M. Hill
- Book ID
- 108382002
- Publisher
- Elsevier Science
- Year
- 1991
- Tongue
- French
- Weight
- 237 KB
- Volume
- 32
- Category
- Article
- ISSN
- 0040-4039
No coin nor oath required. For personal study only.
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## Abstract (__E__)‐α‐Aryltellurenylvinylstannanes have been synthesized stereoselectively via the hydrozirconation of alkynylstannanes, followed by the reactions with aryltellurenyl iodides. (__E__)‐α‐Aryltellurenylvinylstannanes can undergo sequential cross coupling reactions with both electrophi
## Abstract A facile and highly efficient method for the preparation of __α__‐nitro‐__α__‐diazocarbonyl derivatives by a diazo‐transfer reaction involving (trifluoromethyl)sulfonyl azide has been developed. These substrates undergo a rhodium‐catalyzed cyclopropanation reaction with a variety of alk