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Stereoselective synthesis of (E)-α-aryltellurenylvinylstannanes and their application in the synthesis of stereodefined trisubstituted alkenes

✍ Scribed by Ming-Zhong Cai; Jia-Di Huang; Rong-Li Zhang

Publisher
John Wiley and Sons
Year
2010
Tongue
English
Weight
404 KB
Volume
22
Category
Article
ISSN
0256-7660

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✦ Synopsis

Abstract

(E)‐α‐Aryltellurenylvinylstannanes have been synthesized stereoselectively via the hydrozirconation of alkynylstannanes, followed by the reactions with aryltellurenyl iodides. (E)‐α‐Aryltellurenylvinylstannanes can undergo sequential cross coupling reactions with both electrophiles and nucleophiles in the presence of transition metal complexes to form two carbon‐carbon bonds in the same olefinic carbon leading to trisubstituted alkenes stereoselectively.

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