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The synthesis of some analogs of Δ4,9-3-ketosteroids from 1-vinyl-Δ1(9),5(10)-6-hexalone

✍ Scribed by N.N. Gaidamovich; I.V. Torgov

Book ID
118977099
Publisher
Elsevier Science
Year
1964
Tongue
English
Weight
476 KB
Volume
4
Category
Article
ISSN
0039-128X

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Simple and Convenient Method for the Synthesis of ∆ 9(11) -3-Hydroxy, ∆ 1,4 -and ∆ 1,4,9(11) -3-Ketosteroids by Selective Dehydrogenation of 3-Hydroxy-12-ketosteroids. -Hecogenin (I) can be selectively dehydrogenated to the corresponding title compounds by treatment with excess amounts of DDQ in an