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The synthesis of single enantiomers of trans-alkene-containing mycolic acids

✍ Scribed by Gani Koza; Richard Rowles; Cornelia Theunissen; Juma’a R. Al-Dulayymi; Mark S. Baird


Book ID
108285725
Publisher
Elsevier Science
Year
2009
Tongue
French
Weight
620 KB
Volume
50
Category
Article
ISSN
0040-4039

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I1R, 12S)-Lactobacillic acid (1) has been prepared either from D-mannitol by asymmetric cyclopropanation or from cis-cy¢lopropane-l, 2-dimethanol by enzymatic dssymmetfisation. The syntheses of (IIS 12R)-lactobacillic acid ( 2) and (1R, 2S) l-(3'-methoxycmbonyipropyl)-2-octadecylcyciopropane (26) an