The synthesis of oxygen analogs of cepham. A new bicyclic system
β Scribed by John C. Sheehan; Miroslav Dadiac
- Book ID
- 112121842
- Publisher
- Journal of Heterocyclic Chemistry
- Year
- 1968
- Tongue
- English
- Weight
- 330 KB
- Volume
- 5
- Category
- Article
- ISSN
- 0022-152X
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Photolysis of 3-acyl-2-thiotetrahydro-1,3\_thiazines followed by acetylation gave bicyclic B-lactams accompanied by Type II cleavage products. High temperature photolysis of them gave 2,9-dithia-6-azabicyclo[4,3,Olnonan-
## Abstract magnified image __cis__βFused bicyclic acetals were obtained from the unusual cyclization reaction between diols and dihydropyran. Furothiopyran, substituted pyranopyrans, and pyranooxepine and pyranobenzoxepine compounds were obtained with high diastereoselectivity and __cis__βdiaster