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A new method for the synthesis of bicyclic pyran acetals

✍ Scribed by Duygu Ergunes; Volkan Kumbaraci; Bekir Karliga; Naciye Talinli


Publisher
Journal of Heterocyclic Chemistry
Year
2007
Tongue
English
Weight
253 KB
Volume
44
Category
Article
ISSN
0022-152X

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✦ Synopsis


Abstract

magnified image

cis‐Fused bicyclic acetals were obtained from the unusual cyclization reaction between diols and dihydropyran. Furothiopyran, substituted pyranopyrans, and pyranooxepine and pyranobenzoxepine compounds were obtained with high diastereoselectivity and cis‐diastereomers were obtained in high yields.


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