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A new total synthesis of (±)-desacetylcephalothin lactone. A synthesis of novel furo[3,4-c]cephams.

✍ Scribed by J.A. Edwards; A. Guzman; R. Johnson; P.J. Beeby; J.H. Fried

Book ID
104234953
Publisher
Elsevier Science
Year
1974
Tongue
French
Weight
211 KB
Volume
15
Category
Article
ISSN
0040-4039

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Synthesis and Reactions of a Novel Furo [3,4-d]oxazole. -The novel title compound (V), obtained by Rh-catalyzed decomposition of the diazo precursor, undergoes [4 + 2] cycloadditions with usual dienophiles. Density functional theoretical studies are in qualitative agreement with experimental data.