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The Synthesis of Laurolactam from Cyclododecanone via a Beckmann Rearrangement

โœ Scribed by Taber, Douglass F.; Straney, Patrick J.

Book ID
120231152
Publisher
American Chemical Society
Year
2010
Tongue
English
Weight
542 KB
Volume
87
Category
Article
ISSN
0021-9584

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โœ Rogelio P. Frutos; Denice M. Spero ๐Ÿ“‚ Article ๐Ÿ“… 1998 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 202 KB

The synthesis of chiral, nonracemic, fully protected a,a-disubstituted a-amino acids via the Beckmann rearrangement of tosylated oximes 1 is described. The desired amino acids were obtained in good yields with excellent enantioseleetivities in relatively few steps.