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A new synthesis of imidoyl iodides via beckmann rearrangement of oxime sulfonates

โœ Scribed by Yasuko Ishida; Satoru Sasatani; Keiji Maruoka; Hisahi Yamamoto


Book ID
104221501
Publisher
Elsevier Science
Year
1983
Tongue
French
Weight
243 KB
Volume
24
Category
Article
ISSN
0040-4039

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Olefinic cyclization promoted by beckman
โœ Soichi Sakane; Keiji Maruoka; Hisashi Yamamoto ๐Ÿ“‚ Article ๐Ÿ“… 1983 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 203 KB

The acid-catalyzed cyclization of olefinic oxime mesylates has been successfully applied for the synthesis of g-muscone and related macrocycles. We have recently shown that a double bond may become involved in the Lewis acid-catalyzed rearrangement of a suitably constituted olefinic oxime sulfonate