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The Synthesis of Ethyl α-(p-Chlorophenyl)-6,7-dimethoxy-2-methyl- 1,2,3,4-tetrahydro-1-isoquinolinepropionate

✍ Scribed by Morrison, Glenn C.; Shavel, John

Book ID: 127025708
Publisher: American Chemical Society
Year: 1965
Tongue: English
Weight: 279 KB
Volume: 8
Category: Article
ISSN: 0022-2623
DOI: 10.1021/jm00326a028

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(−)‐1‐(p‐Chlorostyryl‐2‐acetyl‐6,7‐dimethoxy‐1, 2,3,4‐tetrahydro‐isoquinoline (IX), which has the same configuration as the analgetic substance (−)‐Ro 4‐1778/1 (I), has been correlated with (+)‐calycotomine (V) of known absolute configuration. Thus the absolute configuration of (−)‐I as (R)‐l‐(p‐chl