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The Synthesis of CP-263,114 and CP-225,917: Striking Long-Range Stereocontrol in the Fashioning of C7

✍ Scribed by Qiang Tan; Samuel J. Danishefsky

Publisher: John Wiley and Sons
Year: 2001
Tongue: English
Weight: 45 KB
Volume: 40
Category: Article
ISSN: 0044-8249
DOI: 10.1002/1521-3773(20010216)40:4<647::aid-anie6473>3.0.co;2-g

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The stunning molecular structures [1] coupled with the promising biological activities of the CP compounds (pho-moidrides, [2] 1 a and b; Figure 1) have inspired numerous studies directed at their total synthesis. [3] In 1999 we reported the first total synthesis of these molecules in their racemic