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The synthesis, characterization and X-ray crystal structure of the rhenium organodiazenido, organodiazene complex [ReCl2(PPh3) (NNC5H4N) (HNNC5H4N)]

✍ Scribed by T. Nicholson; J. Cook; A. Davison; D.J. Rose; K.P. Maresca; J.A. Zubieta; A.G. Jones


Book ID
108328425
Publisher
Elsevier Science
Year
1996
Tongue
English
Weight
286 KB
Volume
252
Category
Article
ISSN
0020-1693

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✍ Antonio Antiñolo; Iván Dorado; Mariano Fajardo; Andrés Garcés; Isabel López-Sol 📂 Article 📅 2004 🏛 John Wiley and Sons 🌐 English ⚖ 254 KB 👁 1 views

## Abstract The preparation of a family of dinuclear monocyclopentadienyl imidoniobium and ‐tantalum complexes was achieved by two different synthetic routes. The diimido complexes [{M(Cp′)Cl~2~}~2~(μ‐1,__i__‐NC~6~H~4~N)] [Cp′ = η^5^‐C~5~H~4~SiMe~3~, M = Nb, __i__ = 4 (1); Cp′ = η^5^‐C~5~H~4~SiMe~3