Synthesis and structural characterization of osmium cluster complexes containing 2-phenylazopyridine. Crystal structures of [Os3(CO)10(NC5H4NNC6H5)] and [Os3(CO)10(μ-H)(NC5H3NN(O)C6H5)]
✍ Scribed by Yat-Kun Au; Kung-Kai Cheung; Wing-Tak Wong
- Publisher
- Elsevier Science
- Year
- 1995
- Tongue
- English
- Weight
- 281 KB
- Volume
- 238
- Category
- Article
- ISSN
- 0020-1693
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## Abstract The preparation of a family of dinuclear monocyclopentadienyl imidoniobium and ‐tantalum complexes was achieved by two different synthetic routes. The diimido complexes [{M(Cp′)Cl~2~}~2~(μ‐1,__i__‐NC~6~H~4~N)] [Cp′ = η^5^‐C~5~H~4~SiMe~3~, M = Nb, __i__ = 4 (1); Cp′ = η^5^‐C~5~H~4~SiMe~3
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