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The Synthesis and Substituent Effect of the Acid Catalyzed Hydrolysis of Amidosulfites

โœ Scribed by Kutuk, Halil; Bekdemir, Yunus; Turkoz, Nalan

Book ID
126645568
Publisher
Taylor and Francis Group
Year
2006
Tongue
English
Weight
109 KB
Volume
181
Category
Article
ISSN
1042-6507

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โœ Martin J.P. Harger; Andrew J. Macpherson; David Pickering ๐Ÿ“‚ Article ๐Ÿ“… 1975 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 128 KB

Haake and Tyssee' postulated a dissociative (Al or Al-like) mechanism for the acidcatalysed hydrolysis of diphenylphosphinanilides 1. They considered cleavage of theP-N bond in the protonated anilide to be well advanced in the transition state 2 and nucleophilic participation by water to be small. A