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The Synthesis and Structure of Pentacarbonyl (5H-dipyrrolo[1,2-c: 2′,1′-e]imidazol-5-yl)manganese

✍ Scribed by Ulrich Burger; Celia Perret; Gérald Bernardinelli; E. Peter Kündig

Publisher
John Wiley and Sons
Year
1984
Tongue
German
Weight
281 KB
Volume
67
Category
Article
ISSN
0018-019X

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✦ Synopsis

Abstract

The dipyrroloimidazolyl ligand is found to bind the pentacarbonylmanganese group to its central ring via a carbon‐metal σ‐bond. This bonding mode differs greatly from that of known imidazole complexes and from the pentahapto mode encountered with the isoelectronic fluorenyl ligand. The X‐ray structure of the title compound is reported.

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