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The synthesis and photochemistry of bicyclo[4.2.0]octa-2,4,7-trienes

โœ Scribed by Ronald N. Warrener; Ian W. McCay; Richard Y.S. Tan; Richard A. Russell


Publisher
Elsevier Science
Year
1979
Tongue
French
Weight
237 KB
Volume
20
Category
Article
ISSN
0040-4039

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โœฆ Synopsis


Two new crystaZZine bicyclo[4.2.OIocta-2,4,7-trienes have been prepared by photodecarbonylation of the a,v$q+L$; structures confirmed by tricyc~o[4.2.1.0 2~5]nona-3,7-dien-9-ones and their The tztle compounds alI undergo thermal ring opening to cyclooctatetmenes, but photolysis is substituent dependent.


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As part of our interestlp2 . I.II the preparation of the 8-oxatricyclo[4.3.0.07"]nona-2,4diene ring system Q), we investigated the epoxidation of bicyclo[4.2.O]octa-2,4,7-trienes (biCOTs) (2). While several examples of epoxidation of cyclobutene a-systems have been reported3, and even the preferenti

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## Abstract Die cyclischen Schwefelsรคureester **4a, d** und **e** werden aus **1a, d** und **e** mit Schwefelsรคure bei Raumtemperatur dargestellt. Bei hรถherer Temperatur entstehen die Diketone **3a** oder **b**. Sowohl die Thermolyse der Schwefelsรคureester bei 180โ€“200ยฐC als auch ihre Sรคurehydrolyse