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The rearrangement of vinyl epoxides derived from bicyclo[4.2.0]Octa-2,4,7-trienes

✍ Scribed by Ronald N. Warrener; Richard A. Russell; Richard Y.S. Tan

Publisher: Elsevier Science
Year: 1978
Tongue: French
Weight: 232 KB
Volume: 19
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(01)94611-8

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✦ Synopsis

As part of our interestlp2 . I.II the preparation of the 8-oxatricyclo[4.3.0.07"]nona-2,4diene ring system Q), we investigated the epoxidation of bicyclo[4.2.O]octa-2,4,7-trienes (biCOTs) (2). While several examples of epoxidation of cyclobutene a-systems have been reported3, and even the preferential epoxidation of a ring-strained n-bond in the presence of a 1,3-diene

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