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The synthesis and fluxional behavior of the first [2.1.2.1] metacyclophane

✍ Scribed by Reginald H. Mitchell; Yee Hing Lai

Publisher
Elsevier Science
Year
1980
Tongue
French
Weight
205 KB
Volume
21
Category
Article
ISSN
0040-4039

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✦ Synopsis

is synthesised. Variable temperature 1Hmr and 13Cmr spectra indicate that4e is the most likely conformation and that at temperatures above 50°C the molecule is fluxional (AGATE = 15.4 kcal/mole).

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