The N-protected 1,10-diaza[2.2]metacyclo-and 1,10-diaza-the hypothesis that 7 is one of the most strained antihetera[2.2]metacyclophanes known. This is also evident from [2]metacyclo[2](2,6)-pyridinophanes 4 and 5 have been synthesized for the first time using high dilution conditions. the 1 H-NMR s
ChemInform Abstract: The First 1,10-Diaza[2.2]metacyclophanes — Strained Medium Membered Heterocycles.
✍ Scribed by M. HABEL; C. NIEDERALT; S. GRIMME; M. NIEGER; F. VOEGTLE
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 28 KB
- Volume
- 29
- Category
- Article
- ISSN
- 0931-7597
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✦ Synopsis
The First 1,10-Diaza[2.2]metacyclophanes -Strained Medium Membered Heterocycles.
-The title compounds are prepared using high dilution techniques. Compound (Ic) is one of the most strained antihetera[2.2]metacyclophanes known, as evidenced by NMR spectroscopy and quantum chemical calculations.
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