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The Synthesis and Cyclization of Some o-Benzylphenones 1,2

โœ Scribed by Vingiello, Frank A.; Oot, James G. Van; Hannabass, H. Hayden

Book ID
126227543
Publisher
American Chemical Society
Year
1952
Tongue
English
Weight
391 KB
Volume
74
Category
Article
ISSN
0002-7863

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โœ Jollie D Godfrey Jr.; Richard H Mueller; Derek J Von Langen ๐Ÿ“‚ Article ๐Ÿ“… 1986 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 218 KB

The cyclization of hydroxamate 1 unexpectedly afforded two isomeric @lactams 2 and 1. The mechanism for the formation of 2 has been shown by carbon-13 labeling to involve a novel 1,2-acyl migration-cyclization process.