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The synthesis and biological activity of 25,26-dihydroxy-cholecalciferol, A polar metabolite of vitamin D3

โœ Scribed by J. Redel; P.A. Bell; N. Bazely; Y. Calando; F. Delbarre; E. Kodicek

Book ID
118978021
Publisher
Elsevier Science
Year
1974
Tongue
English
Weight
572 KB
Volume
24
Category
Article
ISSN
0039-128X

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Stereoselective synthesis of (25R)-25,26
Stereoselective synthesis of (25R)-25,26-dihydroxy-23-oxovitamin D3 and its enzymatic conversion to (25R)-1ฮฑ,25,26-trihydroxy-23-oxovitamin D3, a putative metabolite of vitamin D3
โœ Sachiko Yamada; Keiko Nakayama; Hiroaki Takayama; Toshimasa Shinki; Tatsuo Suda ๐Ÿ“‚ Article ๐Ÿ“… 1984 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 256 KB

25l?)-25,26-Dihydroxy-23-oxovitamin D3 was synthesized efficiently and stereoselectively, and it was converted enzymatically to (25R\_)-lcr,25,26-trihydroxy-23-oxovitamin D3, a putative metabolite of la,25\_dihydroxyvitamin D3. The spectral and chemical properties of (25R&25,26-dihydroxy-23-oxovitam