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The Syntheses of ι-Trifluoromethyl Amino Acids. II. 1,2 Their Microbiological Activities

✍ Scribed by Walborsky, H. M.; Baum, M.; Loncrini, D. F.

Book ID
120013987
Publisher
American Chemical Society
Year
1955
Tongue
English
Weight
541 KB
Volume
77
Category
Article
ISSN
0002-7863

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Lewis acid activation of chiral 2-trifluoromethyl-1,3-oxazolidines. Application to the stereoselective synthesis of trifluoromethylated amines, α- and β-amino acids
✍ Nicolas Lebouvier; Christophe Laroche; Florent Huguenot; Thierry Brigaud 📂 Article 📅 2002 🏛 Elsevier Science 🌐 French ⚖ 84 KB

The reaction of chiral 2-trifluoromethyl-1,3-oxazolidines with various silylated nucleophiles under Lewis acid activation provides a stereoselective route to functionalized a-trifluoromethylamines. This methodology was successfully applied to the diastereoselective synthesis of trifluoromethylated h