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Effects of the Trifluoromethyl Group. IV. 1,2 the pK's of ι-Trifluoromethyl Amino Acids

✍ Scribed by Walborsky, H. M.; Lang, J. H.

Book ID
126473490
Publisher
American Chemical Society
Year
1956
Tongue
English
Weight
364 KB
Volume
78
Category
Article
ISSN
0002-7863

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Lewis acid activation of chiral 2-triflu
Lewis acid activation of chiral 2-trifluoromethyl-1,3-oxazolidines. Application to the stereoselective synthesis of trifluoromethylated amines, α- and β-amino acids
✍ Nicolas Lebouvier; Christophe Laroche; Florent Huguenot; Thierry Brigaud 📂 Article 📅 2002 🏛 Elsevier Science 🌐 French ⚖ 84 KB

The reaction of chiral 2-trifluoromethyl-1,3-oxazolidines with various silylated nucleophiles under Lewis acid activation provides a stereoselective route to functionalized a-trifluoromethylamines. This methodology was successfully applied to the diastereoselective synthesis of trifluoromethylated h