Notes - Basic Alcoholysis of the Trifluoromethyl Group in 1,1,1-Trifluoro-2,2-diarylethanes
β Scribed by Mechoulam, R.; Cohen, S.; Kaluszyner, A.
- Book ID
- 126161737
- Publisher
- American Chemical Society
- Year
- 1956
- Tongue
- English
- Weight
- 391 KB
- Volume
- 21
- Category
- Article
- ISSN
- 0022-3263
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
In the base-promoted dehydrochlorinT;ion of I.i-dichloro-2,2-diphenyiethane-l-C and its D-nitro analog, the isotope effects, k/ k, are 1.045 and 1.024, respectively. These results support an.Elcb-like E2 mechanism for both elimination reactions.
## Abstract The thermal decomposition of 1,1,1βtrifluoroβ2βchloroethane has been investigated in the singleβpulse shock tube between 1120Β° and 1300deg;K at total reflected shock pressures from βΌ2610 to 3350 torr. Under these conditions, the major reaction is the Ξ±,Ξ±βelimination of hydrogen chloride