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Isotope effects and mechanism in the base-promoted dehydrochlorination of 1,1-dichloro-2,2-diarylethanes-1- 14C

✍ Scribed by Agnes Pulay; Arthur Fry

Publisher
Elsevier Science
Year
1986
Tongue
French
Weight
244 KB
Volume
27
Category
Article
ISSN
0040-4039

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✦ Synopsis

In the base-promoted dehydrochlorinT;ion of I.i-dichloro-2,2-diphenyiethane-l-C and its D-nitro analog, the isotope effects, k/ k, are 1.045 and 1.024, respectively. These results support an.Elcb-like E2 mechanism for both elimination reactions.

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