During the search for the lipase formation stimulating factor in Sclerotinia libertiana, one of the authors (Y .S.) succeeded in isolating the active substance, C13H1404 (MS m/e 234), m.p. 123' , [ a]D+7.850, which was designated sclerin (2). Further study on this compound revealed a number of inter
The syntheses of sclerin and sclerolide, metabolites of sclerotinia libertiana
✍ Scribed by T. Kubota; T. Tokoroyoma; T. Nishikawa; S. Maeda
- Publisher
- Elsevier Science
- Year
- 1967
- Tongue
- French
- Weight
- 168 KB
- Volume
- 8
- Category
- Article
- ISSN
- 0040-4039
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
## Abstract Efficient, mild syntheses of the three major metabolites **2**–**4** of the important antipsychotic drug thioridazine (**1**) have been developed. The cardiotoxic metabolite **2** with a ring sulfoxide moiety was prepared in 96% yield by oxidation of **1** with NaIO~4~ under acidic cond
## Abstract The epoxyquinone natural products SDEF 678 metabolite, speciosin A, speciosin B and speciosin C have been prepared for the first time via a short synthetic route based around the palladium‐catalysed coupling of a halogen‐substituted 1,4‐benzoquinone monoketal, a Diels–Alder/retro‐Diels–