During the search for the lipase formation stimulating factor in Sclerotinia libertiana, one of the authors (Y .S.) succeeded in isolating the active substance, C13H1404 (MS m/e 234), m.p. 123' , [ a]D+7.850, which was designated sclerin (2). Further study on this compound revealed a number of inter
โฆ LIBER โฆ
The structure of sclerin, a metabolite of sclerotinia libertiana
โ Scribed by T. Tokoroyama; T. Kamikawa; T. Kubota
- Publisher
- Elsevier Science
- Year
- 1968
- Tongue
- French
- Weight
- 900 KB
- Volume
- 24
- Category
- Article
- ISSN
- 0040-4020
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The structures of sclerosporin and its aldehydic congener, sclerosporal, have been revised as 1 and 2, respectively, on the basis of detailed spectral analysis of sclerosporal \_ with 360 MHz 'H NMR and their total synthesis. Sclerosporin, a sporogenic substance isolated from Sclerotinia fructicola,