✦ LIBER ✦

The study of substituted benzyl radicals by laser-induced fluorescence

✍ Scribed by T.R. Charlton; B.A. Thrush

Publisher: Elsevier Science
Year: 1986
Tongue: English
Weight: 473 KB
Volume: 125
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(86)87096-8

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✦ Synopsis

The visible absorption spectra of all the monomethylbenzyl and monofluorobenzyl rachcals in the gas phase have been studied by laser-induced fluorescence. The fluorescence lifetimes of the stronger vibronic transltions have been measured. It is concluded that, unlike benzyl itself, a single excited electronic state, probably 2A,, 1s involved except for p-methylbenzyl and perhaps o-fluorobenzyl.

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