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Reactions of the fluorobromocarbene radical studied by laser-induced fluorescence

✍ Scribed by J. R. Purdy; B. A. Thrush

Publisher: John Wiley and Sons
Year: 1981
Tongue: English
Weight: 392 KB
Volume: 13
Category: Article
ISSN: 0538-8066
DOI: 10.1002/kin.550130911

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✦ Synopsis

CFBr radicals produced by the reaction of atomic oxygen with FzCCFBr were monitored in a discharge flow system by fluorescence excited at 424 nm. The rate coefficients for reactions of the CFBr radicals were measured between 298 and 358 K, and the following values were obtained in units of cm3/molec.s: 0 2 < 2 X a t 353 K; NO < lo-'* a t 298 K; FzCCFBr < exp(-533 f 62/T). a t 298 K Clz (1.9 f 0.6) X exp(-762 f 92/T); Brz (1.4 f 0.3) X

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