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A kinetic study of chlorine radical reactions with ketones by laser photolysis technique

✍ Scribed by Bo E. R. Olsson; Mattias Hallquist; Evert Ljungström; Jan Davidsson

Publisher
John Wiley and Sons
Year
1997
Tongue
English
Weight
134 KB
Volume
29
Category
Article
ISSN
0538-8066

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✦ Synopsis

out that also Cl radicals may play an important role for the chemical transformation of organic substances in marine environments [see, for example, ref. 1 -6]. Cl radicals can be formed through the reaction between HCl and OH [1] or through photolysis of chlorine containing molecules, originating from sea-salt aerosols [2,6]. It has been suggested that concentrations of Cl radicals between 10 3 and 10 6 molecules cm Ϫ3 are present in marine atmosphere [1,5 -7]. Since Cl normally reacts very fast it is important to obtain knowledge of reaction rates with organic substances including carbonyl compounds.

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