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Laser-induced fluorescence of the CHF radical

✍ Scribed by M.N.R. Ashfold; F. Castaño; G. Hancock; G.W. Ketley

Publisher
Elsevier Science
Year
1980
Tongue
English
Weight
333 KB
Volume
73
Category
Article
ISSN
0009-2614

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✦ Synopsis

Laser-mduced fluorescence of the x 'A"-% 'A' transition in the gas-phase CHF radical has been observed, foBowing the fo_rmatron of the ground-state radical by 1R multiple-photon dissociation. Radiative kfetimes of four vibroruc states of CHF (A 1 A") are reported. * Throughout tius paper ape values are gven III kcal mol-'. F'g. 1. Laser excltatlon spectrum of the CHF x 'A" (OOO)-X lA'(000) transltlon, with posltions of Q branch band heads marked CHF (2) was formed from the IR hlPD of 5.2 mTorr CHzFCl Hnth the P(20) CO2 laser lme at 9.55 urn The dye laser pulse was delayed 2 5 ~1s from the peak of the CO2 pulse. at wiuch time the fluence dehvered was 50 J cmm2.

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