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The Study of Intramolecular Tandem Radical Cyclizations of Acylsilanes with Radicalphiles Attached on Silicon.

✍ Scribed by Kuo-Hsiang Tang; Fang-Yu Liao; Yeun-Min Tsai


Publisher
John Wiley and Sons
Year
2005
Weight
26 KB
Volume
36
Category
Article
ISSN
0931-7597

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✦ Synopsis


Abstract

For Abstract see ChemInform Abstract in Full Text.


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The radical cyclization of 3-oxopropanenitriles 1a -1e and alkenes 2a -2g with cerium(IV) ammonium nitrate (CAN) in ether solvents was investigated (Tables 1 and2). In the optimization study, 1,3-dioxolane, 1,4-dioxane, 1,2-dimethoxyethane, Et 2 O, and THF were used as ether-based solvents, and the