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ChemInform Abstract: Studies on the Radical Cyclization of 3-Oxopropanenitriles and Alkenes with Cerium(IV) Ammonium Nitrate in Ether Solvents.

โœ Scribed by Mehmet Yilmaz

Publisher
John Wiley and Sons
Year
2011
Weight
39 KB
Volume
42
Category
Article
ISSN
0931-7597

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Studies on the Radical Cyclization of 3-
Studies on the Radical Cyclization of 3-Oxopropanenitriles and Alkenes with Cerium(IV) Ammonium Nitrate in Ether Solvents
โœ Mehmet Yฤฑlmaz ๐Ÿ“‚ Article ๐Ÿ“… 2011 ๐Ÿ› John Wiley and Sons ๐ŸŒ German โš– 155 KB ๐Ÿ‘ 1 views

The radical cyclization of 3-oxopropanenitriles 1a -1e and alkenes 2a -2g with cerium(IV) ammonium nitrate (CAN) in ether solvents was investigated (Tables 1 and2). In the optimization study, 1,3-dioxolane, 1,4-dioxane, 1,2-dimethoxyethane, Et 2 O, and THF were used as ether-based solvents, and the