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Experimental and Theroretical Studies on the Transannular Cyclizations of 3,7-Dimethylenebicyclo[3.3.1]nonane with Polyfluoroalkyl Radicals.

โœ Scribed by Maxim V. Ponomarenko; Yurii A. Serguchev; Bogdan V. Ponomarenko; Gerd-Volker Roeschenthaler; Andrey A. Fokin


Publisher
John Wiley and Sons
Year
2006
Weight
22 KB
Volume
37
Category
Article
ISSN
0931-7597

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The radical cyclization of 3-oxopropanenitriles 1a -1e and alkenes 2a -2g with cerium(IV) ammonium nitrate (CAN) in ether solvents was investigated (Tables 1 and2). In the optimization study, 1,3-dioxolane, 1,4-dioxane, 1,2-dimethoxyethane, Et 2 O, and THF were used as ether-based solvents, and the