Krivoruchko. -Chem. Abst. 1\_1. 50409 (1969). 9) The C-H long range couplings observed between C-4a (681.6) and 6-H (66.89) and between C-3 (675.3) and 3-CH3 (61.24) indicates that the remaining quaternary oxycarbon (680.2) is assignable to C-12b.
The structures of griseusins A and B, new isochromanquinone antibiotics
β Scribed by N. Tsuji; M. Kobayashi; Y. Terui; K. Tori
- Publisher
- Elsevier Science
- Year
- 1976
- Tongue
- French
- Weight
- 359 KB
- Volume
- 32
- Category
- Article
- ISSN
- 0040-4020
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Novel substituted 1,8\_diazaanthraquinone structures of diazaquinomycins A and B were determined by the application of nmr spectroscopy. Diazaquinomycins A') (1) and B (z), produced by Streptomyces sp. OM-704, exhibit antibacterial activities against Gram-positive bacteria and are antimetabolites of
In our screening studlee for new antibiotics produced by streptomycetes, a new eerie6 of basic macrollde complex, numbered YL-704, was leolated from the solvent extract of the culture filtrate of Streptomyces vlatensis var. sp. MCRL 0388. Isolated YL-704 complex was constituted by several antiblotlc
This accounts for 22 carbons and 23 protons. The three missing protons belong to 3 hydroxyl groups, which was confirmed by acetylation of 1 to form a triacetate [3, m/z 528 (M+)].
The structures of carbapenems OA-6129A, B,, B2 and C were determlned by spectroscopy and chemical transformation In the course of our extensive work on carbapenems, B2($) and C($,)') new compounds OA-6129A(l), Bl($), have been isolated as sodium salts from Streptmyces sp. OA-6129 These compounds sho